Basket:
Trending Products
001230 - 1,1-Dibromo-3,3,3-trifluoroacetone

CAS Number 431-67-4 MDL Number MFCD00041362
Boiling Point 111-113° Melting Point
Density 1.98 Purity 98%
Molecular Formula C3HBr2F3O Molecular Weight 269.843
Add to Favourites
Stock and Pricing
Size Pack Price Stock Add
1g £ 10.00 > 10
5g £ 14.00 > 10
25g £ 27.00 > 10
100g £ 83.00 2
Request a Quote
Size Unit Qty Add
To view prices in your local currency and Order Online, please Log In to your account.

The lead times given for non-stock items are estimates based on historical data and available information. For fully accurate availability please enquire. When adding pack sizes please be aware shipping costs can be reduced by multiple quantities of pack sizes(Excepted and Limited Quantites).

Hazards and Precautions

GHS05.gif

Hazard Statements

H314: Causes severe skin burns and eye damage.

Precautionary Statements

P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.

Transport Hazards

UN Number 3265
Packing Group II
Shipping Name corrosive liquid, acidic, organic, n.o.s.
Class
Sub Class
Limited Qty 0.5 L
Excepted Qty Inner(30g/mL)  Outer(500g/mL)
No Image

Search for Certificate of Analysis

Enter your lot number: 

Technical Information

A reagent for synthesis of trifluoromethyl heterocycles.1 Used in synthesis of CF3-substituted triarylethenes by stereoselective threefold cross-coupling reactions with aryl boronic acids,2 formation of trifluoropyruvaldehyde hydrate as a useful intermediate for the synthesis of a fused pyrazine derivative,3 and intramolecular Diels-Alder cycloaddition to S-methylthiosemicarbazide for preparing 3-methylthio-6-trifluoromethyl-1,2,4-triazine.4 Also employed in preparation of imidazolylpyrazolylvinylpyridines as inhibitors of ATP-protein kinase interactions,5 preparation of pyridazinone derivatives as herbicide intermediates,6 and  synthesis of 3,4-disubstituted pyrazole analogues as anti-tumor CDK inhibitors.7

References

1.        Indian J. Chem. Sect. B 198827B, 1051.
2.        Angew. Chem. Int. Ed. 200746, 8659.
3.        J. Org. Chem. 199358, 4033.
4.        Arch. Pharm.  1992325, 349.
5.        WO 2008048503 A2 200804242008
6.        EP 1371638 A1 20031217,  2003.
7.        Cancer Ther. 20043, 1427.