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001496 - Ethyl 2-chloro-3-keto-4,4,4-trifluorobutyrate

CAS Number 363-58-6 MDL Number MFCD00041540
Boiling Point 67-71°/35mm Melting Point
Density 1.39 Purity 90%
Molecular Formula C6H6ClF3O3 Molecular Weight 218.56
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10g £ 16.00 3
25g £ 36.00 1
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Hazards and Precautions

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Hazard Statements

H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.

Precautionary Statements

P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2, foam or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents/container to local regulations.

Transport Hazards

UN Number 1993
Packing Group III
Shipping Name flammable liquid, n.o.s.
Class
Sub Class
Limited Qty 10 L
Excepted Qty Inner(30g/mL)  Outer(1kg/l)
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Technical Information

A reagent for organic synthesis. Applied in reaction with dimethyl isocyanatophosphite to give oxazaphospholine,1 synthesis of a novel class of corticotropin-releasing factor receptor type 1 (CRF1R) antagonists [(6-chloro-2-trifluoromethyl-7-aryl-7H-imidazo[1,2-a]imidazol-3-yl)- methyl]amines,2 synthesis of 2-aminoethyl-5-carbethoxythiazoles,3 synthesis of novel 2-methyl-4-trifluoromethyl-thiazole-5-carboxamide derivatives,4 and synthesis of new trifluoromethylated 1,3-oxazolecarboxanilides.5

Reference

1.        Zh. Obshchei Khim. 199363, 2233.
2.        Bioorg. Medicinal Chem. Lett. 201020, 3669.
3.        Tetrahedron Lett. 200546, 2251.
4.        J. Fluorine Chem. 2004125, 1287.
5.        Agric. Chem. Biotechnol. 200245, 37.