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046132 - Dichloro(1,5-cycloocatadiene)palladium(II)

CAS Number 12107-56-1 MDL Number MFCD00012412
Boiling Point Melting Point
Density Purity 95%
Molecular Formula C8H12Cl2Pd Molecular Weight 285.5
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1g £ 58.00 3
5g £ 244.00 1-2 weeks
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Hazards and Precautions


Hazard Statements

H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary Statements

P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .

None Hazardous for Transport

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Technical Information

A catalyst for C-C bond and C-N formation such as Heck coupling of alkynes with alkenes, and Suzuki cross-coupling of aryl bromides.1 Applied as a catalyst in Suzuki reactions of aryl chlorides with phenylboronic acid in the presence of 1,4-bis(2-hydroxy-3,5-di-tert-butylbenzyl)piperazine,2 arylation of vinylsiloxanes via Heck coupling reaction,3 allylic substitution of oximes with allylic acetate,4 synthesis of 5,5''-dibromo-2,2':6',2''-terpyridine and 5,5'-dibromo-2,2'-bipyridine via coupling of dihalogenopyridines with 5-bromo-2-trialkylstannylpyridines,5  synthesis of benzo[b]thiophenes from thioenols,6 and methoxycarbonylation of iodobenzene.7 Also used as a precursor to prepare novel palladium complexes with different ligands.8,9


1.        Angew. Chem. Int. Ed. Engl. 200847, 2668.
2.        Appl. Organometal. Chem. 201125, 616.
3.        J. Organometal. Chem. 2009694, 3386.
4.        J. Org. Chem. 200570, 5630.
5.        Pol. J. Chem. 200983, 245.
6.        Chem. Comm. 2008, 5529.
7.        Inorg. Chem. Comm. 20036, 823.
8.        Polyhedron 201130, 2574.
9.        Transit. Metal Chem. 201136, 513.
10.    Eur. J. Inorg. Chem. 2011, 3232.