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046169 - Palladium-2,4-pentanedionate

CAS Number 14024-61-4 MDL Number MFCD00000025
Boiling Point Melting Point
Density Purity = 99.9% (Assay, Palladium content: = 34.9%)
Molecular Formula C10H14O4Pd Molecular Weight 304.64
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Stock and Pricing
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250mg £ 21.00 3
1g £ 50.00 1-2 weeks
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Hazards and Precautions


Hazard Statements

H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary Statements

P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .

None Hazardous for Transport

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Technical Information

A catalyst in organic synthesis. Employed in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides,1 Sonogashira coupling reaction of aryl bromides with a variety of terminal alkynes,2 reductive carbonylation of aryl and heteroaryl iodides,3 head-to-tail dimerization of vinylarenes,4  catalytic cycloaddition of diazoalkanes generated in situ to fullerene C60,5 1,1-difunctionalization of activated alkenes,6 and Silaboration of 1,3-enynes.7 Also used for synthesis of bimetallic PdPt nanoparticles,8and synthesis of Highly monodisperse spherical 3 nm Pd-Cu alloy nanoparticles.9


1.        J. Am. Chem. Soc. 2007129, 4824.
2.        Synlett 2011, 1277.
3.        Tetrahedron Lett. 201152, 2383.
4.        Tetrahedron Lett. 201152, 1569.
5.        Russ. J. Org. Chem. 201046, 588.
6.        Eur. J. Org. Chem. 2009, 1313.
7.        Org. Lett. 200810, 2505.
8.        Chem. Mat. 201123, 4199.
9.        Chem. Asian J. 20116, 1515.