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002863 - Silver(II) fluoride

CAS Number 7783-95-1 MDL Number MFCD00003411
Boiling Point Melting Point 690°
Density 4.57 Purity 99%
Molecular Formula AgF2 Molecular Weight 145.865
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25g £ 125.00 > 10
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Hazards and Precautions

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Hazard Statements

H272: May intensify fire; oxidiser.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.

Precautionary Statements

P210: Keep away from – No smoking.
P220: Keep/Store away from clothing//combustible materials.
P221: Take any precaution to avoid mixing with combustibles/
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use for extinction.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.

Transport Hazards

UN Number 3085
Packing Group II
Shipping Name oxidizing solid, corrosive, n.o.s.
Class
Sub Class
Limited Qty 2.5 kg
Excepted Qty Inner(30g/mL)  Outer(500g/mL)
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Technical Information

Silver(II) fluoride is a strong fluorinating and oxidizing agent used in the fluorination and preparation of organic perfluorocompounds.lt is also used in the fluorination of aromatic compounds, although selective monofluorinations are more difficult.2 Silver(II) fluoride also oxidizes xenon to xenon difluoride in anhydrous HF solutions, and carbon monoxide to carbonyl fluoride.3 In recent research involving fluorofullerene preparations it was used in the  fluorination of C60 to yield a new compound C60F44 as the predominant product.4 It has also been used in the  fluorination of highly fluorinated organic compounds.5

1. J. Org. Chem. 1962, 28, 494.
2. J. Org. Chem. 1980, 45, 3597.
3. J. Inorg. Nucl. Chem. 1974, 36, 997.
4. J. Fluorine Chem. 2001, 112, 191.
5. Collect. Czech. Chem. Commun. 2008, 73, 1729.